Product Distributions in the Liquid-phase Oxidation of Cyclohaxane over CoAPO-5.
نویسندگان
چکیده
منابع مشابه
Kinetic Studies of the Catalytic Oxidation of Toluene to Benzoic Acid in the Liquid Phase
The catalytic oxidation of toluene to benzoic acid in the liquid phase has been studied in an un-stirred tank reactor. Low concentration of acetic acid was added in order to increase the solubility of the catalyst in toluene. The dependence of the rate of reaction on the concentration of toluene catalyst and oxygen pressure was studied. It has been suggested that liquid phase oxidation of t...
متن کاملDirect oxidation of benzene to phenol in liquid phase by H2O2 over vanadium catalyst supported on highly ordered nanoporous silica
Vanadium supported on highly ordered nanoporous silica (VOx-LUS-1) was synthesized and characterized by XRD, Nitrogen adsorption‑desorption isotherms and UV-visible spectrophotometer. Direct oxidation of benzene to phenol in liquid phase by H2O2 peroxide were examined by using various solvents (methanol, acetone, acetic acid, acetonitryl). The maximum yield (25%) and selectivity (73%) of the ph...
متن کاملStatistical Optimization of Liquid Phase Oxidation of Benzyl Alcohol over Efficient Cobalt Promoted Vanadyl Pyrophosphate Catalysts by Box-Behnken Design
Vanadium phosphorus oxides (VPO) has been applied as a heterogeneous catalyst in gas phase oxidation reactions and its application is very limited in liquid phase. In this study a series of cobalt-doped vanadium phosphorus oxides (VPO-Co) catalysts with different loading of Co (0.01-1.0 mol ratio of Co/V) were prepared. Oxidation of benzyl alcohol was studied in the liquid phase over VPO and VP...
متن کاملdirect oxidation of benzene to phenol in liquid phase by h2o2 over vanadium catalyst supported on highly ordered nanoporous silica
vanadium supported on highly ordered nanoporous silica (vox-lus-1) was synthesized and characterized by xrd, nitrogen adsorption‑desorption isotherms and uv-visible spectrophotometer. direct oxidation of benzene to phenol in liquid phase by h2o2 peroxide were examined by using various solvents (methanol, acetone, acetic acid, acetonitryl). the maximum yield (25%) and selectivity (73%) of the ph...
متن کاملkinetic studies of the catalytic oxidation of toluene to benzoic acid in the liquid phase
the catalytic oxidation of toluene to benzoic acid in the liquid phase has been studied in an un-stirred tank reactor. low concentration of acetic acid was added in order to increase the solubility of the catalyst in toluene. the dependence of the rate of reaction on the concentration of toluene catalyst and oxygen pressure was studied. it has been suggested that liquid phase oxidation of tolue...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: JOURNAL OF CHEMICAL ENGINEERING OF JAPAN
سال: 1994
ISSN: 0021-9592,1881-1299
DOI: 10.1252/jcej.27.211